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The stereodefined installation of chiral centers adjacent to thermodynamically unstable Z-olefins is a challenge in synthetic chemistry. In a recent work published in Science, You and coworkers reported an iridium-catalyzed,… Click to show full abstract
The stereodefined installation of chiral centers adjacent to thermodynamically unstable Z-olefins is a challenge in synthetic chemistry. In a recent work published in Science, You and coworkers reported an iridium-catalyzed, Z-retentive asymmetric allylic allylation with a variety of Z-allyl esters, providing elegant access to important chiral Z-olefins.
Keywords:
intercepting labile;
anti allyl;
complex isomerization;
labile anti;
iridium complex;
allyl iridium
Journal Title: Chem
Year Published: 2021
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Journal Title: Chem
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!