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Borylation of azines via a Minisci-type reaction

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C–H borylation of N-heteroarenes is an efficient yet highly challenging route to borylated aromatics. In a recent issue of Nature, Leonori and co-workers demonstrated a novel strategy toward this end… Click to show full abstract

C–H borylation of N-heteroarenes is an efficient yet highly challenging route to borylated aromatics. In a recent issue of Nature, Leonori and co-workers demonstrated a novel strategy toward this end by utilizing a boryl-radical-based Minisci-type reaction that shows orthogonal site selectivity to transition-metal-catalyzed approaches.

Keywords: type reaction; borylation azines; minisci type

Journal Title: Chem
Year Published: 2021

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