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Uncovering pseudo-doublet ground states innate to U(IV) complexes through magnetism

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In the June issue of Chem, Chilton, Liddle, and colleagues reported the synthesis and characterization of uranium(IV)-oxo and -imido complexes that exhibit anomalously high low-temperature magnetic moments as a result… Click to show full abstract

In the June issue of Chem, Chilton, Liddle, and colleagues reported the synthesis and characterization of uranium(IV)-oxo and -imido complexes that exhibit anomalously high low-temperature magnetic moments as a result of nearly doubly degenerate spin-orbit ground states. Traditional crystal-field arguments prove paramount in the elucidation of the electronic configuration of the uranium(IV) molecules.

Keywords: uncovering pseudo; ground; ground states; doublet ground; pseudo doublet; states innate

Journal Title: Chem
Year Published: 2021

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