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Superhydrophobic modification of ceramic membranes for vacuum membrane distillation

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Abstract The hydrophobically modified ceramic membranes have great potential for energy-efficient membrane distillation. In this work, flat-sheet ceramic membranes with a superhydrophobic surface were fabricated by grafting 1 H ,1… Click to show full abstract

Abstract The hydrophobically modified ceramic membranes have great potential for energy-efficient membrane distillation. In this work, flat-sheet ceramic membranes with a superhydrophobic surface were fabricated by grafting 1 H ,1 H ,2 H ,2 H -perfluorooctyltrichlorosilane or 1 H ,1 H ,2 H ,2 H -perfluorodecyltriethoxysilane and followed by ultraviolet irradiation. The surface water contact angle was improved from 46° of original ceramic membrane to 159°, which exhibited a stable and excellent superhydrophobic effect. The modified membranes showed a high flux of 27.28 kg·m − 2 ·h − 1 and simultaneously maintained an excellent retention rate of 99.99%, when used in vacuum membrane distillation process for treatment of a 1 wt% NaCl (75 °C) aqueous solution. These results suggested that superhydrophobic modification of ceramic surface is a facile and cost-effective way to achieve higher membrane distillation performance. The superhydrophobically-modified ceramic membrane with an excellent desalination capacity would show considerable potential in practical membrane distillation utilizations.

Keywords: superhydrophobic modification; vacuum membrane; distillation; membrane distillation; ceramic membranes

Journal Title: Chinese Journal of Chemical Engineering
Year Published: 2017

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