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Porous nitrogen-enriched hollow carbon nanofibers as freestanding electrode for enhanced lithium storage

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Abstract One-dimensional porous carbons bearing high surface areas and sufficient heteroatom doped functionalities are essential for advanced electrochemical energy storage devices, especially for developing freestanding film electrodes. Here we develop… Click to show full abstract

Abstract One-dimensional porous carbons bearing high surface areas and sufficient heteroatom doped functionalities are essential for advanced electrochemical energy storage devices, especially for developing freestanding film electrodes. Here we develop a porous, nitrogen-enriched, freestanding hollow carbon nanofiber (PN-FHCF) electrode material via filtration of polypyrrole (PPy) hollow nanofibers formed by in situ self-degraded template-assisted strategy, followed by NH3-assisted carbonization. The PN-FHCF retains the freestanding film morphology that is composed of three-dimensional networks from the entanglement of 1D nanofiber and delivers 3.7-fold increase in specific surface area (592 m2·g-1) compared to the carbon without NH3 treatment (FHCF). In spite of the enhanced specific surface area, PN-FHCF still exhibits comparable high content of surface N functionalities (8.8 at%) to FHCF. Such developed hierarchical porous structure without sacrificing N doping functionalities together enables the achievement of high capacity, high-rate property and good cycling stability when applied as self-supporting anode in lithium-ion batteries, superior to those of FHCF without NH3 treatment.

Keywords: storage; porous nitrogen; carbon; nitrogen enriched; hollow carbon

Journal Title: Chinese Journal of Chemical Engineering
Year Published: 2020

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