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Cs+ immobilization by designed micaceous adsorbent under subcritical conditions

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Abstract The adsorption of Cs + by clay minerals is a complicate process, being cation exchange and frayed-edge sites the major mechanisms that govern it. However, environmental variables have a… Click to show full abstract

Abstract The adsorption of Cs + by clay minerals is a complicate process, being cation exchange and frayed-edge sites the major mechanisms that govern it. However, environmental variables have a significant impact on the process. In this work, the influence of the temperature and time in the cesium adsorption capacity of Na-Mica-n (n = 2 and 4) have been explored under subcritical conditions. Those synthetic micas were able to immobilize cations Cs + combining adsorption at nonspecific sites, at specific sites and chemical reaction. The distribution constant of Cs + was larger in the Na-Mica-2 denoting a higher concentration of specific adsorption sites when layer charge decreased.

Keywords: adsorption; adsorbent subcritical; micaceous adsorbent; immobilization designed; designed micaceous; subcritical conditions

Journal Title: Applied Clay Science
Year Published: 2017

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