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Sustainable catalytic properties of silver nanoparticles supported montmorillonite for highly efficient recyclable reduction of methylene blue

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Abstract Water contamination by organic dyes has become a serious environmental pollution. Here, a facile, green and cost-effective synthesis approach was developed to in situ grow silver nanoparticles (Ag NPs)… Click to show full abstract

Abstract Water contamination by organic dyes has become a serious environmental pollution. Here, a facile, green and cost-effective synthesis approach was developed to in situ grow silver nanoparticles (Ag NPs) on the eco-friendly and low cost natural material montmorillonite (Mt) through dopamine chemistry. The loading amount of silver on the montmorillonite reached 20 mass %. The Ag NPs supported montmorillonite (Ag NPs@Mt) exhibited excellent catalytic performances to reduce a model organic dye methylene blue in the presence of NaBH 4 with catalytic efficiency higher than 98% and apparent reduction rate constant k app higher than 1.70 min − 1 . More importantly, the Ag NPs@Mt was proven to show excellent recyclability for at least 20 cycles and long-term stability for one month soaking in water. This low-cost and recyclable Ag NPs@Mt shows great potential in large scale application to treat dye containing wastewater.

Keywords: reduction; silver nanoparticles; methylene blue; supported montmorillonite; sustainable catalytic

Journal Title: Applied Clay Science
Year Published: 2017

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