LAUSR

Abstract We identified the sources of quartz in shales of the Niutitang Formation in the Cen'gong block, northern Guizhou Province, China, based on thin-section studies using a scanning electron microscope (SEM), rock cores and field observations. By analyzing the petrology, total organic carbon (TOC), major elements, and illite “crystallinity”, we investigated the formation of silica in the Niutitang shales. Our results show that the quartz in the Niutitang shales consists mainly of detrital quartz, biogenic quartz, and quartz that transformed from clay minerals. The amount of excess SiO2 in the Niutitang shales was approximately 5–35%, and the Al/(Fe + Al + Mn) and Si/(Si + Al + Fe) ratios ranged from 0.45 to 0.85 and from 0.7 to 0.91, respectively, which indicates that the silica was not solely biogenic. The values of excess SiO2, Al/(Fe + Al + Mn), Si/(Si + Al + Fe), and TOC increased with increasing quartz content, which implies that increasing quartz concentrations were associated with gradual increases in biogenic quartz and decreases in detrital quartz. Quartz from different sources can result in varying rock geomechanical properties and fracture abundance. Compared with pure biogenic quartz or detrital quartz, an appropriate proportion of mixed biogenic quartz and detrital quartz can make rocks more brittle and therefore lead to more fractures.