Abstract Electrochemistry strongly contributed to deepen the understanding and predictability of atom transfer radical polymerization (ATRP) outcomes. Several electrochemical tools have been used to determine thermodynamic and kinetic parameters that… Click to show full abstract
Abstract Electrochemistry strongly contributed to deepen the understanding and predictability of atom transfer radical polymerization (ATRP) outcomes. Several electrochemical tools have been used to determine thermodynamic and kinetic parameters that are hardly accessible by other techniques. The electrochemical methods presented in this brief review were applied to systems with extremely different ATRP reactivity, providing a rational database of primary reference for further developments of ATRP.
               
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