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Electrochemical approaches for better understanding of atom transfer radical polymerization

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Abstract Electrochemistry strongly contributed to deepen the understanding and predictability of atom transfer radical polymerization (ATRP) outcomes. Several electrochemical tools have been used to determine thermodynamic and kinetic parameters that… Click to show full abstract

Abstract Electrochemistry strongly contributed to deepen the understanding and predictability of atom transfer radical polymerization (ATRP) outcomes. Several electrochemical tools have been used to determine thermodynamic and kinetic parameters that are hardly accessible by other techniques. The electrochemical methods presented in this brief review were applied to systems with extremely different ATRP reactivity, providing a rational database of primary reference for further developments of ATRP.

Keywords: electrochemistry; electrochemical approaches; radical polymerization; transfer radical; atom transfer

Journal Title: Current Opinion in Electrochemistry
Year Published: 2019

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