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Molecular design of ambipolar redox-active open-shell molecules: Principles and implementations

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Abstract The mini-review highlights key structural features and provides guidelines for the molecular design of ambipolar redox-active frameworks, which are of interest for the fabrication of all-organic ‘poleless’ batteries and… Click to show full abstract

Abstract The mini-review highlights key structural features and provides guidelines for the molecular design of ambipolar redox-active frameworks, which are of interest for the fabrication of all-organic ‘poleless’ batteries and semiconductors. Open-shell molecules that can form at least three relatively stable redox states (i.e. cationic, neutral, and anionic) are discussed. The efficiency of the suggested strategies is supported by the representative examples taken from the recent publications.

Keywords: open shell; molecular design; redox; redox active; ambipolar redox; design ambipolar

Journal Title: Current Opinion in Electrochemistry
Year Published: 2020

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