LAUSR

Abstract The redox-mediated electrochemical-chemical process, when it involves the redox-targeting reaction with energy materials, has shown intriguing potential for various energy-related applications. This review starts with a brief discussion on the evolution of redox-targeting reactions for high energy redox-flow batteries and the critical future studies for large-scale energy storage. Then, with spatially decoupled water electrolysis as an example, the merits of redox-targeting reaction by liberating the catalyst from electrode surface are highlighted, followed by an introduction of redox targeting-based thermal-to-electrical conversion. We have also featured various redox-targeting processes in other fields of study, such as electrochromic window, redox catalysis, and spent battery material recycling, etc. Overall, this review attempts to demonstrate the incredible versatility and prospects of redox-targeting process for energy-related applications.