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One-step synthesis of Ag@SiO2@Ag nanomaterial and its application as hydrogen peroxide sensor

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Abstract Ag@SiO2@Ag core-shell structure nanomaterial was synthesized by a simple one-step method, and applied to electrochemical sensing detection of H2O2. The results of transmission electron microscope (TEM), X-ray diffraction (XRD)… Click to show full abstract

Abstract Ag@SiO2@Ag core-shell structure nanomaterial was synthesized by a simple one-step method, and applied to electrochemical sensing detection of H2O2. The results of transmission electron microscope (TEM), X-ray diffraction (XRD) and energy dispersive spectrometry (EDS) verified the morphology, structure and composition of Ag@SiO2@Ag nanomaterial. The current response of the Ag@SiO2@Ag sensor was linearly toward to concentration of H2O2 between 0.005 mM and 24.0 mM with a detection limit of 1.7 μM at a signal-to-noise ratio of 3. The sensitivity was 56.07 μA mM−1 cm−2. The Ag@SiO2@Ag/GCE exhibited wide linear range and high sensitivity for electrochemical detection of H2O2.

Keywords: synthesis sio2; sio2 nanomaterial; step synthesis; one step; nanomaterial application

Journal Title: Colloids and Surfaces A: Physicochemical and Engineering Aspects
Year Published: 2017

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