LAUSR

Abstract Calcium borate 2CaO·B 2 O 3 ·H 2 O nanoflake and nanobelt have been prepared under hydrothermal conditions, which were characterized by the XRD (X-ray diffraction), FT-IR (Fourier transform infrared spectroscopy), TGA (thermogravimetric analysis), SEM (scanning electron microscope) and TEM (transmission electron microscope). Their thermodynamic parameters were also obtained by calorimetry method through an appropriate thermochemical cycle, showing that their thermal stabilities decreased gradually with the decrease of 2CaO·B 2 O 3 ·H 2 O sizes. The flame retardant properties of the prepared 2CaO·B 2 O 3 ·H 2 O nanomaterials were investigated by a non-isothermal decomposition kinetic method and limited oxygen index method. With the decrease of TG mass loss, the decrease of heat release for DSC, the increase of LOI values, and the increase of apparent activation energy E a , the flame retardant properties of prepared 2CaO·B 2 O 3 ·H 2 O samples are increased gradually from non-nanostructure to nanobelts then to nanoflakes, which may be ascribed to their sizes being decreased accordingly. The possible flame retarding mechanism has been proposed. It can be predicted that 2CaO·B 2 O 3 ·H 2 O nanoflakes could serve as a potential flame retardant.