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A binder-free electrode based on Ti3C2Tx-rGO aerogel for supercapacitors

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Abstract MXene, a new two-dimensional (2D) material, has been extensively studied in the field of energy storage. However, the restacking and inferior stability of MXene severely affect their development. Herein,… Click to show full abstract

Abstract MXene, a new two-dimensional (2D) material, has been extensively studied in the field of energy storage. However, the restacking and inferior stability of MXene severely affect their development. Herein, we fabricated a Ti3C2Tx-rGO aerogel through ascorbic acid-assisted hydrothermal treatment. It could effectively reduce the restacking of MXene and enhance the electrochemical properties of electrode material. The redox kinetics of electrode materials were analyzed. The diffusion-controlled process contributions from Ti3C2Tx/rGO-4 were significantly higher than Ti3C2Tx owing to the more exposed active sites after reduced graphene oxide (rGO) intercalation and increased layer spacing. Ti3C2Tx/rGO-4 aerogel binder-free electrode achieved a special capacitance of 313 F g−1 (about 174 % of Ti3C2Tx) at 1 A g−1. Moreover, Ti3C2Tx/rGO-4 symmetric supercapacitor demonstrated an outstanding energy density of 7.5 Wh kg−1 at a power density of 500 W kg−1 when the operated potential was at 1 V, showing a good application prospect.

Keywords: free electrode; ti3c2tx rgo; binder free; rgo; rgo aerogel

Journal Title: Colloids and Surfaces A: Physicochemical and Engineering Aspects
Year Published: 2020

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