LAUSR

Abstract This study compared the interfacial adhesion properties of asphalt with limestone aggregate and asphalt with granite aggregate. The main chemical compositions of limestone and granite aggregate were analyzed using X-ray diffraction XRD. A dynamic shear rheometer (DSR) test was conducted to examine the rheological performance of the original asphalt, limestone-asphalt mortar, and granite-aggregate mortar. X-ray photoelectron spectroscopy (XPS) was applied to detect whether a chemical shift occurred between aggregate and asphalt, to analyze the adhesion function. The results show that the interfacial adhesion strength of the asphalt with limestone aggregate is higher than that of the asphalt with granite aggregate. The main chemical constituent of limestone is CaCO 3 , and the main chemical constituent of granite is SiO 2 . Limestone-asphalt mortar samples and granite-asphalt mortar samples were prepared by mixing original asphalt with pure CaCO 3 and SiO 2 powders, respectively. The limestone-asphalt mortar has lower phase angle than the original asphalt, whereas the phase angle of granite-asphalt mortar differs slightly from that of original asphalt. Carbon, oxygen, and sulfur are the main elements of asphalt, and in particular, the sulfoxide group has an influence on the adhesion property of asphalt. The adhesion function of the limestone aggregate with asphalt may depend on the migration of the outermost orbital electrons of Ca 2+ to the active functional group in the asphalt, resulting in the formation of a new chemical bond. The adhesion function of the granite aggregate with asphalt is determined only in terms of its physical adhesion with the asphalt.