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Analysis of atomistic structural deformation characteristics of calcium silicate hydrate in 53-year-old tricalcium silicate paste using atomic pair distribution function

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Abstract Although the atomistic structure and the deformation characteristics of calcium silicate hydrates (C-S-H) are of primary interest in cement chemistry, they have not been fully investigated. In this study,… Click to show full abstract

Abstract Although the atomistic structure and the deformation characteristics of calcium silicate hydrates (C-S-H) are of primary interest in cement chemistry, they have not been fully investigated. In this study, pair distribution function (PDF) analysis was conducted on a 53-year-old fully hydrated tricalcium silicate (C3S) paste using in situ synchrotron high-energy X-ray scattering to probe the atomic structural deformation of C-S-H under external loading. The results were compared with those from our previous PDF study of a 131-day-old C3S paste in order to elucidate the effect of aging on the mechanical characteristics of C-S-H. Three different strains measured by the strain gauge, by the lattice shifts (d-spacing) in the reciprocal space, and by the shift of the interatomic distance (r) in the real space were compared. In the range of r

Keywords: paste; silicate; deformation; characteristics calcium; deformation characteristics; calcium silicate

Journal Title: Construction and Building Materials
Year Published: 2020

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