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Microstructure evolution and high-temperature mechanical properties of SiCf/SiC composites in liquid fluoride salt environment

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Abstract High temperature mechanical properties and microstructure evolution of chemical-vapor-infiltrated SiC fiber reinforced SiC ceramic matrix composites (SiC f /SiC) in 46.5LiF-11.5NaF-42.0KF (mol.%, FLiNaK) eutectic salt were investigated. The results… Click to show full abstract

Abstract High temperature mechanical properties and microstructure evolution of chemical-vapor-infiltrated SiC fiber reinforced SiC ceramic matrix composites (SiC f /SiC) in 46.5LiF-11.5NaF-42.0KF (mol.%, FLiNaK) eutectic salt were investigated. The results indicate that the corrosion of SiC f /SiC composites was accelerated with increase of corrosion temperature. Interlayer boundaries in SiC matrix with higher oxygen content were corroded preferentially. The F − formed Si F coordinate bond with SiC and replaced carbon, followed by the corrosion of SiC matrix. While single SiC fiber tensile strength suffered no depravation after corrosion, corrosion and damage of SiC matrix led to deteriorated high temperature mechanical properties of SiC f /SiC composites.

Keywords: temperature; high temperature; corrosion; temperature mechanical; mechanical properties; sic composites

Journal Title: Corrosion Science
Year Published: 2017

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