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Correlation of surface Volta potential with galvanic corrosion initiation sites in solid-state welded Ti-Cu bimetal using AFM-SKPFM

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Abstract This study aims to correlate the microstructure and Volta potential distribution of Ti-Cu welded bimetal to its corrosion initiation sites, using AFM-SKPFM, and SEM-EDS. Local melted zones with Ti-Cu… Click to show full abstract

Abstract This study aims to correlate the microstructure and Volta potential distribution of Ti-Cu welded bimetal to its corrosion initiation sites, using AFM-SKPFM, and SEM-EDS. Local melted zones with Ti-Cu intermetallic precipitates in weld interface and in Cu matrix showed different Volta potential values in comparison with those of Ti and Cu regions. SKPFM revealed that Cu region has a higher Volta potential than that of Ti region. AFM and microstructural images after immersion in corrosive media proved the presence of a galvanic cell. Corrosion mainly extends on Cu side due to the increasing growth of Ti passive film.

Keywords: corrosion initiation; using afm; welded bimetal; corrosion; volta potential; initiation sites

Journal Title: Corrosion Science
Year Published: 2018

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