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Effect of spinel and perovskite coatings on the long term oxidation of a ferritic stainless steel in H2/H2O atmosphere

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Abstract In order to improve the oxidation behaviour of AISI441 ferritic stainless steel in H2/H2O atmosphere at 800 °C, four oxide coatings were tested: two perovskites (La0.8Sr0.2MnO3 and LaNi0.6Fe0.4O3) deposited by… Click to show full abstract

Abstract In order to improve the oxidation behaviour of AISI441 ferritic stainless steel in H2/H2O atmosphere at 800 °C, four oxide coatings were tested: two perovskites (La0.8Sr0.2MnO3 and LaNi0.6Fe0.4O3) deposited by screen printing and two spinels (MnCo2O4 and Co3O4) obtained by PVD technique. Isothermal oxidation tests performed up to 3000 h showed that the coating presence avoided Fe oxides growth, which occurs for the raw alloy in the same conditions. Moreover, a protective (Cr,Mn)3O4/Cr2O3 layer formed between the substrate and the coating. Any presence of Cr was not detected within the coatings, indicating that all compositions were efficient in preventing Cr evaporation.

Keywords: h2o atmosphere; oxidation; steel h2o; stainless steel; ferritic stainless

Journal Title: Corrosion Science
Year Published: 2019

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