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Sulfide ions-induced release of biocides from a metal-phenolic supramolecular film fabricated on aluminum for inhibition of microbially influenced corrosion

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Abstract Herein, we fabricate a novel metal-phenolic supramolecular film on aluminium, which can control release of loaded biocides when S2− concentration is higher than 10 mM or in sulfate reducing bacteria… Click to show full abstract

Abstract Herein, we fabricate a novel metal-phenolic supramolecular film on aluminium, which can control release of loaded biocides when S2− concentration is higher than 10 mM or in sulfate reducing bacteria (SRB) environment with a long incubation period. The protection effect of the film on microbially influenced corrosion (MIC) induced by SRB is analyzed with fluorescence microscopy and electrochemical measurement. A novel microbiological corrosion protection mechanism is proposed based on its effective roles to suppress SRB settlement and insulate corrosive medium. The intelligent film maintains a longtime antibacterial behavior owing to its S2--responsive character, which enhances the microbiological corrosion resistance.

Keywords: supramolecular film; metal phenolic; corrosion; film; phenolic supramolecular; microbially influenced

Journal Title: Corrosion Science
Year Published: 2020

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