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Early oxidation stages of a Co-Cr-Fe-Mn-Ni-Si complex concentrated alloy with Cr, Mn, and Si contents matching those of 316L stainless steel

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Abstract A complex concentrated Co-Cr-Fe-Mn-Ni-Si alloy with increased configurational entropy and contents of Cr, Mn, and Si corresponding to those in 316L stainless steel was studied with respect to its… Click to show full abstract

Abstract A complex concentrated Co-Cr-Fe-Mn-Ni-Si alloy with increased configurational entropy and contents of Cr, Mn, and Si corresponding to those in 316L stainless steel was studied with respect to its oxidation behavior. Early-stage oxidation was investigated for annealing at 400 °C and 800 °C. In addition to Cr, considerable amounts of Fe, Co, and Ni were found in the oxide, and nodules formed at 800 °C. In contrast to 316L, on which a protective corundum-type oxide forms during oxidation, the formation of spinel-type oxide was observed to dominate both at low and high temperature.

Keywords: complex concentrated; oxidation; 316l stainless; stainless steel; concentrated alloy

Journal Title: Corrosion Science
Year Published: 2021

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