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Design, preparation and properties of high-performance Z-scheme Bi2MoO6/g-C3N4-x composite photocatalyst

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Abstract g-C3N4-x with nitrogen-deficient structure was prepared by raising the thermal etching temperature to 625 °C, and Bi2MoO6 was prepared through hydrothermal synthesis. The Bi2MoO6/g-C3N4-x composite photocatalyst with electron transfer mechanism… Click to show full abstract

Abstract g-C3N4-x with nitrogen-deficient structure was prepared by raising the thermal etching temperature to 625 °C, and Bi2MoO6 was prepared through hydrothermal synthesis. The Bi2MoO6/g-C3N4-x composite photocatalyst with electron transfer mechanism as Z-scheme was then synthesized through joint heating at 400 °C. Mechanism analysis indicated that the formation of the nitrogen deficiency and Z-scheme carrier transport path in Bi2MoO6/g-C3N4-x composite photocatalyst can reduce the recombination rate of photogenerated electron-holes and prolong the lifetime of photogenerated carriers. 0.50 Bi2MoO6/g-C3N4-x had the highest photocatalytic activity, whose degradation rates reached 95% after 1 h irradiation, more than twice the photocatalysis effect of original g-C3N4.

Keywords: c3n4 composite; bi2moo6 c3n4; composite photocatalyst; c3n4

Journal Title: Chemical Physics Letters
Year Published: 2020

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