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Enhanced dielectric properties of halloysite/PVDF-HFP modified by Li-ion realizing superior energy conversion ability

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Abstract High dielectric material has attracted interest in applications of triboelectric nanogenerators for its high charge-trapping capability. We reported the enhancement of both dielectric and piezoelectric properties by adding modified… Click to show full abstract

Abstract High dielectric material has attracted interest in applications of triboelectric nanogenerators for its high charge-trapping capability. We reported the enhancement of both dielectric and piezoelectric properties by adding modified halloysite (HAL) into PVDF-HFP. Due to the combined effect of triboelectric generation by enhanced dielectric constant and piezoelectric generation by increase of β-phase, the HAL/PVDF-HFP composites film modified by Li+ and water exhibited superior generated current of 9.23 × 10−7 A compared to the pure PVDF-HFP with 1.65 × 10−7 A and unmodified HAL/PVDF-HFP with 2.68 × 10−7 A. This work is expected to inspire the design and fabrication of high dielectric and piezoelectric material for nanogenerators.

Keywords: dielectric properties; enhanced dielectric; hal pvdf; pvdf hfp; hfp

Journal Title: Chemical Physics Letters
Year Published: 2020

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