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Differential cross sections and product ro-vibrational distributions for 16O+36O2 and 18O+32O2 exchange reactions

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Abstract We report the rotational-state resolved integral cross sections and differential cross sections for 18 O + 16 O 16 O (v=0,j=1) → 18 O 16 O ( v ′… Click to show full abstract

Abstract We report the rotational-state resolved integral cross sections and differential cross sections for 18 O + 16 O 16 O (v=0,j=1) → 18 O 16 O ( v ′ =0, j ′ ) + 16 O and 16 O + 18 O 18 O (v=0,j=1) → 18 O 16 O ( v ′ =0, j ′ ) + 18 O reactions obtained using time-independent quantum mechanical method on an ab-initio potential energy surface of ozone [Dawes et al., J. Chem. Phys. 135, 081102 (2011)]. The results for both the reactions in the collision energy range of 0.001 –0.1 eV are presented and discussed the isotopic effects found. The present results are compared with the earlier experimental and theoretical results reported in the literature.

Keywords: distributions 16o; product vibrational; cross sections; vibrational distributions; differential cross; sections product

Journal Title: Chemical Physics Letters
Year Published: 2021

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