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Cd0.9Co0.1S nanostructures concentration study on the structural and optical properties of SWCNTs/PVA blend

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Abstract In the current work, the effect of Cd0.9Co0.1S nanostructures concentration as fillers on the structure and optical properties of single-walled carbon nanotubes/polyvinyl alcohol (SWCNTs/PVA) blend has been explored. Different… Click to show full abstract

Abstract In the current work, the effect of Cd0.9Co0.1S nanostructures concentration as fillers on the structure and optical properties of single-walled carbon nanotubes/polyvinyl alcohol (SWCNTs/PVA) blend has been explored. Different concentrations of Cd0.9Co0.1S nanostructures filled SWCNTs/PVA nanocomposites were prepared via casting technique. FT-IR spectroscopy was used to examine the structures’ variation of the prepared samples. XRD technique was applied to explore the structural properties. XRD analysis reveals that the prepared filler possesses a nanostructured nature with a simple cubic structure. While the XRD measurements of all filled SWCNTs/PVA nanocomposites exhibit amorphous characters. The optical properties were explored using a UV-Vis-NIR spectrophotometer. The obtained direct bandgap of the filled samples decreases from 5.34 to 4.92 eV as filler’s concentration is increased from 0 to 10 wt%. Enhancement of the optical parameters (refractive index, dielectric permittivity and optical conductivity) of SWCNTs/PVA blend could be achieved via Cd0.9Co0.1S nanostructures filling. The prepared Cd0.9Co0.1S filled SWCNTs/PVA nanocomposites could play a great role in optoelectronic and energy storage applications.

Keywords: swcnts pva; 9co0 nanostructures; pva blend; nanostructures concentration; optical properties; cd0 9co0

Journal Title: Chemical Physics Letters
Year Published: 2021

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