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Thermal conductivity of Cu-Ti/diamond composites via spark plasma sintering

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Abstract Copper matrix composites reinforced with 50 vol% diamond particles were prepared by spark plasma sintering. The diamond particles, Cu-Ti alloy powder and Cu power were mixed in different mass ratios… Click to show full abstract

Abstract Copper matrix composites reinforced with 50 vol% diamond particles were prepared by spark plasma sintering. The diamond particles, Cu-Ti alloy powder and Cu power were mixed in different mass ratios and sintered at a temperature of 925 °C for 10 min in vacuum. Effects of Ti content on microstructure and thermal conductivity of the Cu-xTi/diamond composites were studied in the range of 0–1 wt%. With Ti content increasing, the thermal conductivity of the Cu-Ti/diamond composites increases first and then decreases. The highest thermal conductivity of 529 W/(m·K) was obtained in the Cu-0.2Ti/diamond composite owing to the improved interfacial bonding and lower interfacial thermal resistance. The diffuse mismatch model and Hasselman-Johnson model were used to calculate the theoretical thermal conductivity of the Cu-Ti/diamond composites. It is shown that moderate content of Ti addition is good for improving the thermal conductivity of Cu/diamond composites, which is consistent with experimental results.

Keywords: conductivity diamond; thermal conductivity; spark plasma; diamond; diamond composites

Journal Title: Diamond and Related Materials
Year Published: 2019

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