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Fabrication of symmetric supercapacitor based on relatively long lifetime polyaniline grown on reduced graphene oxide via Fe2+ oxidation sites

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Abstract Reduced graphene oxide and polyaniline (RGO-PANI) composite was prepared via functionalized ferrite on graphene oxide as corresponding PANI nucleation sites, which dramatically increase the composite specific capacitance and lifetime… Click to show full abstract

Abstract Reduced graphene oxide and polyaniline (RGO-PANI) composite was prepared via functionalized ferrite on graphene oxide as corresponding PANI nucleation sites, which dramatically increase the composite specific capacitance and lifetime when compared with crude PANI. Symmetric paper-based supercapacitors (SCs) were fabricated and electrochemically tested using different electrolytes namely; KOH, H2SO4, H3PO4 and Na2SO4. Therefore, strong alkaline, strong acid, weak acid and natural electrolytes impact on the composite was studied. The influence of various electrolytes was studied intensively using Bio-Logic VSP-300 where cyclic voltammetry, Galvanostatic charge/discharge and impedance spectroscopy tests were applied. The highest achieved specific capacitance was more than 500 F/g of pure electric double layer behavior coupled with 100% retention after 5000 cycles. The composite was characterized using X-ray diffraction, scanning electron microscopy, Raman spectroscopy, and transmission electron microscopy.

Keywords: microscopy; symmetric supercapacitor; reduced graphene; spectroscopy; fabrication symmetric; graphene oxide

Journal Title: Diamond and Related Materials
Year Published: 2019

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