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Thermal explosion of a reactive gas mixture at constant pressure for non-uniform and uniform temperature systems

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Abstract In this study, the approximate and exact solutions for the stationary-state of the solids model with neglecting reactant consumption for both non-uniform and uniform temperature systems applied on gas… Click to show full abstract

Abstract In this study, the approximate and exact solutions for the stationary-state of the solids model with neglecting reactant consumption for both non-uniform and uniform temperature systems applied on gas ignition under constant pressure condition. The criticality conditions for a slab, an infinite cylinder, and a sphere are determined and discussed using dimensionless temperatures under constant ambient and surface temperatures for a non-uniform temperature system. Exact solution for a Semenov model with convection heat loss was also presented. The solution of the Semenov problem for constant volume or density as a solid and constant pressure were compared. The critical parameter δ is calculated and compared with those of Frank-Kamenetskii solution values. The validation of the calculated ignition temperatures with other exact solution and experimental results were offered. The relation between critical parameters form Semenov and F.K. models solution was introduced.

Keywords: non uniform; uniform temperature; solution; constant pressure

Journal Title: Defence Technology
Year Published: 2021

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