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Threshold voltage modulation of polymer transistors by photoinduced charge–transfer between donor–acceptor dyads

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Abstract In this work, the photoinduced optoelectronic properties of a conjugated polymer from device characterization and quantum calculations have been studied. It was demonstrated that the photosensitive conjugated polymer with… Click to show full abstract

Abstract In this work, the photoinduced optoelectronic properties of a conjugated polymer from device characterization and quantum calculations have been studied. It was demonstrated that the photosensitive conjugated polymer with electron donor–acceptor dyad (6) which contains a terthiophene unit, can modulate charge accumulation by photoirradiation resulting in a threshold voltage shift in the polymer field-effect transistors (PFETs) while this effect of the photoinactive polymer (5) containing a thienothiophene unit is negligible. These results suggest that the feasible molecular design strategies can provide an effective platform to achieve controllable threshold voltage modulation in PFETs.

Keywords: voltage; charge; threshold voltage; donor acceptor; voltage modulation

Journal Title: Dyes and Pigments
Year Published: 2017

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