Abstract Host-guest systems have attracted increasing interest in designing stimuli-responsive devices in recent years. In this paper, a photo-switchable supramolecular ultrathin films (UTFs) with high on/off contrast and good reversibility… Click to show full abstract
Abstract Host-guest systems have attracted increasing interest in designing stimuli-responsive devices in recent years. In this paper, a photo-switchable supramolecular ultrathin films (UTFs) with high on/off contrast and good reversibility has been constructed based on the host-guest assembly between cationic layered double hydroxide (LDH) nanosheets and anionic [Eu(SiW10MoO39)2]13− (denoted as EuSiWMo). The luminescence of the UTFs can be efficiently quenched under UV light (
               
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