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A template-free synthesis via alkaline route for Nb 2 O 5 /carbon nanotubes composite as pseudo-capacitor material with high-rate performance

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Abstract In this paper, we report a facile template-free method to prepare the T-Nb2O5/CNTs composite. The addition of ammonia induces the electrostatic interaction between functionalized CNTs and niobic acid colloids… Click to show full abstract

Abstract In this paper, we report a facile template-free method to prepare the T-Nb2O5/CNTs composite. The addition of ammonia induces the electrostatic interaction between functionalized CNTs and niobic acid colloids during hydrothermal process, resulting in CNTs homogeneously distributed in the T-Nb2O5 phase. The obtained T-Nb2O5/CNTs composite shows high rate Li+ storage ability with typical intercalation capacitive behaviour. The presence of well-dispersed CNTs in Nb2O5 can apparently reduce the limitation from diffusion process and increase the high rate charge-discharge capability. From the galvanostatic tests, a capacity of ∼180 mAh g−1 at 1 A g−1 and ∼130 mAh g−1 at 5 A g−1 is attained.

Keywords: free synthesis; rate; high rate; template free; synthesis via; via alkaline

Journal Title: Electrochimica Acta
Year Published: 2017

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