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Lysine-modified TiO2 nanotube array for optimizing bioelectricity generation in microbial fuel cells

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Abstract As the carrier of electroactive bacteria and part of the electron migration path, the anode is a restricting factor for the power density of microbial fuel cells (MFCs). In… Click to show full abstract

Abstract As the carrier of electroactive bacteria and part of the electron migration path, the anode is a restricting factor for the power density of microbial fuel cells (MFCs). In this study, carbon-coated TiO2 nanotube array (TNT/HL) was synthesized by anodization and thermal treatment, for use as anodes in MFCs to promote power production. Due to the sucker structure and the carbon attachment, the TNT/HL anode increased the bacterial loading capacity when exposed under lamplight or natural light. Single-chamber MFCs with the TNT/HL anode achieved a maximum power density of 0.88 W/m2, which is much higher than that of MFCs using the common commercial carbon cloth (CC) anode (0.61 W/m2). Further investigation attributed such superior results to the better biocompatibility, enlarged electroactive surface, decreased electric resistance and Tafel slope of the as-prepared TNT/HL anode. This study introduces a promising anode material for MFCs with high conductivity, high current density, and fast extracellular electron transfer (EET).

Keywords: nanotube array; microbial fuel; anode; tio2 nanotube; fuel cells

Journal Title: Electrochimica Acta
Year Published: 2019

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