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Catalytic hydrothermal liquefaction of eucalyptus to prepare bio-oils and product properties

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Abstract Catalytic hydrothermal liquefaction of eucalyptus was performed in the presence of NaOH, KOH, and Pd/C at 260 and 300 °C. The influences of catalyst and temperature on the process were… Click to show full abstract

Abstract Catalytic hydrothermal liquefaction of eucalyptus was performed in the presence of NaOH, KOH, and Pd/C at 260 and 300 °C. The influences of catalyst and temperature on the process were thoroughly investigated regarding product distribution and characteristics of the bio-oil obtained. The yields of bio-oils obtained using NaOH and KOH were 61.2% and 57.7% for the liquefaction at 260 °C, respectively. For the liquefaction with alkali catalysts, as the liquefaction temperature increased, the yields of bio-oils and solid residue decreased, while the amounts of gas and losses increased. The C and H contents of heavy oils were higher than those in light oils, and the O content was lower than those in light oils. GC–MS analysis of the sample indicated that the bio-oils contained large amounts of carboxylic acids, aldehydes, ketones, phenols, and esters. The liquid products are promising bio-fuel precursors for further utilization.

Keywords: liquefaction eucalyptus; catalytic hydrothermal; bio oils; hydrothermal liquefaction; liquefaction

Journal Title: Energy Conversion and Management
Year Published: 2019

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