LAUSR.org creates dashboard-style pages of related content for over 1.5 million academic articles. Sign Up to like articles & get recommendations!

Encapsulating sulfur in δ-MnO2 at room temperature for Li-S battery cathode

Photo from wikipedia

Abstract Sulfur is a promising alternative lithium battery cathode for its low cost, abundance, and high specific capacity. However, issues of rapid capacity decay and low coulombic efficiency hamper its… Click to show full abstract

Abstract Sulfur is a promising alternative lithium battery cathode for its low cost, abundance, and high specific capacity. However, issues of rapid capacity decay and low coulombic efficiency hamper its practical application pace owing to polysulfides dissolution. Despite efforts on hybridizing sulfur with metal oxides to solve these issues are considered to be effective, the synthesis of hybrid materials is always tedious. Herein, S@MnO2 hybrid material was synthesized via a green method at room temperature. We encapsulate S spheres in poly-dopamine (PDA) by in-situ polymerization of dopamine. The formed PDA shell is served as reducing agent and sacrificial template to transform KMnO4 into δ-MnO2 shell without adding any other agents (such as acid). δ-MnO2 encapsulates the S spheres uniformly and succeeded in entrapping polysulfides when S@MnO2 used for Li–S battery, endowing the S@MnO2 cathode with high reversible capacity, improved cycling stability, and satisfied coulombic efficiency. Moreover, this method could be adopted for hybridizing δ-MnO2 with diverse materials (such as CNTs@MnO2) in mild reaction environment (ambient pressure and temperature), exhibiting an extensive application on constructing Mn-based oxide hybrid functional materials.

Keywords: battery; mno2; room temperature; battery cathode

Journal Title: Energy Storage Materials
Year Published: 2017

Link to full text (if available)


Share on Social Media:                               Sign Up to like & get
recommendations!

Related content

More Information              News              Social Media              Video              Recommended



                Click one of the above tabs to view related content.