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Synthesis of plasma treated nitrogen-doped graphite oxide for supercapacitor applications

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Abstract Herein plasma treated nitrogen-doped graphite oxide (P-N-GO) is synthesized by using ammonium hydroxide solution and plasma for supercapacitor applications. Nitrogen is doped 10 at%, and electrochemical active surface area… Click to show full abstract

Abstract Herein plasma treated nitrogen-doped graphite oxide (P-N-GO) is synthesized by using ammonium hydroxide solution and plasma for supercapacitor applications. Nitrogen is doped 10 at%, and electrochemical active surface area is increased almost three times, compared to the precursor graphite oxide. Electrochemical impedance is also dramatically reduced from 221 to 29 Ω at 100 Hz. Resultant capacitance of the composite is 201 Fg−1, which is about four times larger than that of precursor graphite oxide (∼60 Fg−1) at the scan rate of 50 mVs−1, demonstrating high energy density of 11 Whkg−1 when its power density reaches to 166 Wkg−1. The capacitance retention is 89% after 2000 cycles, revealing high cyclic stability and reliable performance for the supercapacitor applications.

Keywords: nitrogen doped; graphite oxide; plasma treated; supercapacitor applications; treated nitrogen

Journal Title: Journal of energy storage
Year Published: 2019

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