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Structurally controlled synthesis of calcium sulphate dihydrate from industrial wastes of spent sulphuric acid and limestone

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Abstract All types of gypsum binders are obtained mainly from the natural gypsum and man-made products. As a sustainable analogue of these materials, synthetic gypsum as a product of spent… Click to show full abstract

Abstract All types of gypsum binders are obtained mainly from the natural gypsum and man-made products. As a sustainable analogue of these materials, synthetic gypsum as a product of spent dilute sulphuric acid and calcium carbonate was proposed. We investigated the effect of various technological parameters on the production of calcium sulphate dihydrate particles with a given morphology. The sizes of calcium sulphate dihydrate crystals with optimal values of technological parameters and exposure time up to 4.5 h increased from 18 to 28 μ m and combined into agglomerates with sizes that mostly lie in the range from 200 to 600 μ m. Synthesized calcium sulphate crystals acquiring a prismatic shape instead of a needle shape which simplified and accelerated the industrial filtration process. Our study shows that a promising sustainable and cheap source of gypsum-containing raw materials is synthetic gypsum, obtained by reacting a suspension of calcium carbonate and spent sulphuric acid.

Keywords: calcium; sulphate dihydrate; sulphuric acid; calcium sulphate

Journal Title: Environmental Technology and Innovation
Year Published: 2020

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