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LaCoO3 catalytically enhanced MgO partially stabilized ZrO2 in heterogeneous methane combustion

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Abstract Heterogeneous combustion is an advanced combustion technique in which a porous ceramic support is immersed into a combustion chamber to provide heat redistribution through the chemical reaction wave. Within… Click to show full abstract

Abstract Heterogeneous combustion is an advanced combustion technique in which a porous ceramic support is immersed into a combustion chamber to provide heat redistribution through the chemical reaction wave. Within this work a support made of magnesia partially stabilized zirconia (MgO-ZrO 2 ), a fast O 2- ionic conductor, is used to evaluate gadolinia doped ceria (Ce 0.8 Gd 0.2 O 1.9 ), and lanthanum cobaltite (LaCoO 3 ) as solid catalysts to promote lean methane combustion. By utilizing temperature profiles of the combustion chamber, collection of radiative and acoustic emissions, it was found that both Ce 0.8 Gd 0.2 O 1.9 and LaCoO 3 are effective combustion catalysts, with LaCoO 3 being even better performing, which enable higher maximum temperatures within the combustion chamber and extend lean flammability limits of methane-air combustion.

Keywords: methane combustion; partially stabilized; combustion; combustion chamber; lacoo3 catalytically

Journal Title: Experimental Thermal and Fluid Science
Year Published: 2018

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