Photo by des0519 from unsplash
The temperature-composition phase diagram of the two-component system 1-Br-adamantane and 1-Cl-adamantane has been determined by means of thermal analysis techniques and X-ray powder diffraction from the low-temperature phase to the… Click to show full abstract
The temperature-composition phase diagram of the two-component system 1-Br-adamantane and 1-Cl-adamantane has been determined by means of thermal analysis techniques and X-ray powder diffraction from the low-temperature phase to the liquid state. The crossed isopolymorphism formalism has been applied to the two-component system to infer the normal pressure properties of the orthorhombic metastable phase of 1-Cl-adamantane at normal pressure. The experimental pressure-temperature phase diagrams for the involved compounds are related to the two-phase equilibria determined at normal pressure and inferences about the monotropic behavior of the aforementioned orthorhombic phase are discussed.
Journal Title: Fluid Phase Equilibria
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!