LAUSR.org creates dashboard-style pages of related content for over 1.5 million academic articles. Sign Up to like articles & get recommendations!

Densities, viscosities, and refractive indices of binary and ternary mixtures of methanol, acetone, and chloroform at temperatures from (298.15–318.15) K and ambient pressure

Photo by hope_house_press_leather_diary_studio from unsplash

Abstract Densities, viscosities, and refractive indices of binary and ternary liquid systems of methanol, acetone, and chloroform at temperatures from)298.15–318.15(K and ambient pressure were measured. In this regard, it should… Click to show full abstract

Abstract Densities, viscosities, and refractive indices of binary and ternary liquid systems of methanol, acetone, and chloroform at temperatures from)298.15–318.15(K and ambient pressure were measured. In this regard, it should be stressed that the measurements covered the whole composition range of the components in the binary and the ternary systems. In addition, the experimental data have been utilized in order to extract some derived properties like excess molar volume (VE), viscosity deviation (Δη), and refractive index deviation (ΔnD). To correlate the aforementioned derived properties, the well-known Redlich-Kister and Cibulka equations were applied on the binary and ternary mixtures, respectively. Consequently, the control parameters, as well as the corresponding standard deviations, were completely reported. Moreover, for further validation, the McAllister three-body interaction model for kinematic viscosity and Grunberg-Nissan model for dynamic viscosity were examined and the results were thoroughly compatible with the Redlich-Kister polynomial equation. By using the derived properties, the nature of the intermolecular interactions and the hydrogen bond between solvents in the binary and ternary mixtures were discussed and the results are satisfying in terms of matching to the theoretical models.

Keywords: refractive indices; indices binary; viscosities refractive; ternary mixtures; densities viscosities; binary ternary

Journal Title: Fluid Phase Equilibria
Year Published: 2019

Link to full text (if available)


Share on Social Media:                               Sign Up to like & get
recommendations!

Related content

More Information              News              Social Media              Video              Recommended



                Click one of the above tabs to view related content.