LAUSR

Abstract Photocatalysts based on calcined ZnAl layered double hydroxides were obtained by coprecipitation and the subsequent thermal treatments at different temperatures. The calcined materials were characterized and its photocatalytic behavior was evaluated in the water splitting reaction in presence of UV irradiation. According to the XRD analysis, there was detected the presence of Zn as hexagonal ZnO in all the samples, as well as Al forming ZnAl 2 O 4 and Zn 6 Al 2 O 9 , depending on the temperature of calcination employed. H 2 yield was higher as the annealing temperature was increased due to the formation of the heterojunctions of ZnO with the Zn 6 Al 2 O 9 and ZnAl 2 O 4 oxides, reaching the maximum value in the sample annealed at 600 °C. Some decay in the activity was observed in the sample calcined at 700 °C, probably due to the higher recombination rate of the photogenerated charge carriers in that heterojunction in comparison with that obtained at 600 °C.