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Mechanism studies on the application of the mixed cationic/anionic surfactant systems to enhance oil recovery

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Abstract Mixed cationic/anionic surfactant systems have showed great potential in various fields. Ionic liquids with extraordinary physical and chemical properties are regarded as novel alternatives to traditional surfactants. In this… Click to show full abstract

Abstract Mixed cationic/anionic surfactant systems have showed great potential in various fields. Ionic liquids with extraordinary physical and chemical properties are regarded as novel alternatives to traditional surfactants. In this report, we evaluated the performances of the mixed surfactant systems comprising a cationic surface-active ionic liquid 1-dodecyl-3-methylimidazolium chloride (M12) and an anionic surfactant sodium dodecyl sulfate (SDS) in terms of surface/interfacial tension reduction, emulsifying ability, wettability alteration and core flooding tests. Molecular dynamic simulation was employed to explore the surface/interfacial activity of the mixed surfactant systems. The interfacial tension (IFT) between the mixed surfactant solutions and crude oil could be dramatically decreased to the ultralow level (

Keywords: surfactant systems; anionic surfactant; mixed cationic; cationic anionic; oil

Journal Title: Fuel
Year Published: 2019

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