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Inverse correlation between the molybdenum and uranium isotope compositions of Upper Devonian black shales caused by changes in local depositional conditions rather than global ocean redox variations

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Abstract Coupled Mo-U isotope data from the Upper Devonian Kettle Point Formation (Ontario, Canada) provide a cautionary tale regarding interpretation of global ocean redox conditions using data from euxinic black… Click to show full abstract

Abstract Coupled Mo-U isotope data from the Upper Devonian Kettle Point Formation (Ontario, Canada) provide a cautionary tale regarding interpretation of global ocean redox conditions using data from euxinic black shales. In the Gore of Chatham core, the Kettle Point black shales have high Mo concentrations (48–473 μg/g) and consistently high Mo/U ratios (≥3 times the Mo/U ratio of modern seawater), suggesting a euxinic depositional environment. These shales yield an inverse correlation (r = 0.89, p

Keywords: global ocean; isotope; black shales; upper devonian; ocean redox; inverse correlation

Journal Title: Geochimica et Cosmochimica Acta
Year Published: 2020

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