LAUSR

Abstract The skeleton water-extractable fines (SWEF) is a soil fraction smaller than 2 mm located at the interface between rock fragments (RF) and fine earth (FE). It is made of illuvial and/or RF weathering products comprising neoformed clay-size particles and organic substances. Contrary to FE and even to soil RF, SWEF represents a poorly documented soil fraction despite its unique ion exchange properties. To fill this knowledge gap, we compared mineralogy, effective cation exchange capacity (ECEC), and exchangeable cation composition of SWEF with those of FE and RF from three acidic soils derived from either mica schist (Mottarone, Italy), granite (Aubure, France) or glacial till of varied lithology (Gardsjon, Sweden), and subjected to distinct climatic conditions. Further, we provided a general hypothesis on the formation of SWEF. The SWEF had a different acidity level, a significantly higher accumulation of organic C, a higher Al p and/or Fe p content (in two over three soils), was enriched in neoformed minerals, and had a larger concentration of exchangeable cations than both FE and RF. A key role in the development of the SWEF properties was attributed to mineralogy, weathering and pedogenesis. The interactions between mineralogical composition, pH, and organic C content not only determined the extent of ECEC in SWEF but also the source of exchangeable cations originating either from organic complexes (Mottarone soil) or from the dissolution of the mineral phases (Aubure and Gardsjon soils). However, the abundance of SWEF appeared to be independent from the actual abundance of RF. Its formation was rather controlled by the combination of mineralogy of the parent material, weathering intensity, pathway of mineral dissolution (congruent and/or incongruent dissolution), and to the duration of pedogenesis.