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Lithium benzenechromiumtricarbonyl as C-nucleophile in the cross-dehydrogenative coupling reactions of azaaromatics

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Abstract Direct, non-catalyzed by transition metals, the oxidative cross-dehydrogenative coupling reactions (CDC) of azines with lithium benzenechromiumtricarbonyl has been developed. A series of previously unknown benzenechromiumtricarbonyl derivatives of azines, as… Click to show full abstract

Abstract Direct, non-catalyzed by transition metals, the oxidative cross-dehydrogenative coupling reactions (CDC) of azines with lithium benzenechromiumtricarbonyl has been developed. A series of previously unknown benzenechromiumtricarbonyl derivatives of azines, as well as intermediates of these reactions, have been obtained and characterized by NMR and X-ray analysis.

Keywords: cross dehydrogenative; lithium benzenechromiumtricarbonyl; coupling reactions; benzenechromiumtricarbonyl; dehydrogenative coupling

Journal Title: Inorganica Chimica Acta
Year Published: 2019

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