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Abstract Three new hydrogen bonding motifs of phosphine oxides involving a silanol, a phenol, and chloroform are described. The single crystal X-ray structures, in combination with the NMR and IR… Click to show full abstract
Abstract Three new hydrogen bonding motifs of phosphine oxides involving a silanol, a phenol, and chloroform are described. The single crystal X-ray structures, in combination with the NMR and IR data of the new adducts Ph3PO∙HOSiPh2OSiPh2OH·OPPh3, which features a linear Si–O–Si linkage, Cy3PO·HO(2,6-tBu2-4-Me(C6H2), and Cy3PO·HCCl3, are reported and discussed.
Keywords:
phosphine oxides;
phenol chloroform;
motifs phosphine;
bonding motifs;
new hydrogen;
hydrogen bonding
Journal Title: Inorganica Chimica Acta
Year Published: 2019
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Journal Title: Inorganica Chimica Acta
Year Published: 2019
Link to full text (if available)
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recommendations!