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A chromone derivative as a colorimetric and “ON-OFF-ON” fluorescent probe for highly sensitive and selective detection of Cu2+ and S2−

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Abstract A chromone derivative (L) which could be utilized for reversibly detecting Cu2+ and S2− by means of fluorescence quenching and displacement in aqueous solution was designed and developed. Upon… Click to show full abstract

Abstract A chromone derivative (L) which could be utilized for reversibly detecting Cu2+ and S2− by means of fluorescence quenching and displacement in aqueous solution was designed and developed. Upon the addition of Cu2+, the strong blue-green fluorescence emission of L was quenched rapidly and then recovered in 1 min by successively adding S2−. Furthermore, with the alternate addition of Cu2+ and S2−, the reversible cycles could be repeated for at least four times, which meant that L could be identified as a renewable dual-functioning probe. What's more, due to its excellent sensing performances, this probe L could also be used to detect Cu2+ and S2− with test strips conveniently.

Keywords: derivative colorimetric; probe; colorimetric fluorescent; cu2; chromone derivative

Journal Title: Inorganica Chimica Acta
Year Published: 2021

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