LAUSR

This study proposed a sustainable method to prepare cellulose I nanocrystals (CNCs I) from microcrystalline cellulose (MCC) in a mildly acidic lithium bromide trihydrate (MALBTH) system, a concentrated (50 wt%) solution of LiBr in water with recyclable formic acid (FA). First, the MCC was treated in the MALBTH system to generate CNCs with a uniform size, yield higher than 68.49% and crystallinity of 84.02%. Then, the CNCs could application for stabilizing Pickering emulsions for at least 15 days. Furthermore, FA was easily recycled from the MALBTH system, and the yield of the CNCs produced from the hydrolysis of MCC by using the recycled FA was still higher than 60%. Finally, this study provided a sustainable and green production of CNCs. A low-cost and environmentally friendly pathway to recover FA from the MALLBTH system at a high yield was still realized.