LAUSR

Abstract Ni-Mo2C particles supported over hydroxyapatite were synthesized as potential catalysts to hydrogen production applications due their physiochemical properties observed in characterization results, this favorable for biomass gasification. Mo2C particles doped with Ni were synthesized by temperature programmed reaction method at 900 °C under hydrogen reducing atmosphere. Hydroxyapatite support was obtained from thermal extraction of bovine bones, in a temperature range from 700 to 900 °C. Ni-Mo2C impregnation over hydroxyapatite support was made by incipient humidity method. X-ray diffraction analysis determined crystallographic phases of β-Mo2C, NiC and hydroxyapatite. Though, bone organic matter degradation was observed by X-ray diffraction and confirmed by Infrared Spectroscopy with Fourier Transform (FTIR) the final structure of hydroxyapatite was maintained. Finally, textural properties analysis of support showed an increase in porosity structure with the increment of temperature. β-Mo2C and NiC were obtained with similar catalytic activity than noble metals, also nickel improves hydrocarbons bonds rupture. Hydroxyapatite showed high stability and porosity at elevated temperatures attributable to synthesis conditions.