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Transparent nanostructured Co doped NiO thin films deposited by sol‒gel technique

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Abstract In this work, the effect of annealing temperature (540, 560, 580 and 600 °C) on synthesis of Co doped NiO thin films were investigated. Co doped NiO thin films were… Click to show full abstract

Abstract In this work, the effect of annealing temperature (540, 560, 580 and 600 °C) on synthesis of Co doped NiO thin films were investigated. Co doped NiO thin films were deposited by spin coating method with molarity of 0.8 mol.l−1 at room temperature. The XRD analyses showed that the NiO films have a cubic structure with high crystallite size of in Co doped NiO thin film is 82.57 nm of (200) plane was obtained at 580 °C. This is to improvement the structure crystallinity. The optical transmission showed that the band gap energy was found increases from 3.2265 to 3.8382 eV at 600 °C. At high annealing temperature, the Co doped NiO thin films having a less disorder and fewer defects with minimum Urbach energy was 266 meV at 600 °C. The calculate refractive indices were found in qualitative agreement to the values derived from Reddy, Kumar and Ravindra models. P‒type semiconducting Co doped NiO thin films’ having a maximum value of the electrical conductivity was found at 580 °C. The annealing temperature at 580 °C the Co doped NiO thin films have a good crystallinity, optical and electrical conductivity.

Keywords: thin films; nio thin; films deposited; doped nio; annealing temperature

Journal Title: Optik
Year Published: 2018

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