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A micromechanical-based model of stimulus responsive liquid crystal elastomers

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Abstract Stimulus responsive elastomers are advanced engineered materials that perform desired functionalities when triggered by external stimuli. Liquid crystal elastomers (LCEs) are one important example that exhibit reversible actuation when… Click to show full abstract

Abstract Stimulus responsive elastomers are advanced engineered materials that perform desired functionalities when triggered by external stimuli. Liquid crystal elastomers (LCEs) are one important example that exhibit reversible actuation when cycled above and below their nematic-to-isotropic transition temperature. Here, we propose a micromechanical-based model that is centered on the evolution of the chain distribution tensor of the LCE network. Our model, framed within the statistical model of the chain network, enables a mesoscale description of their mechanical response under an external thermal stimulus. We compare the model to prior experimental observations of the bending response of 3D printed LCE elements with controlled director alignment.

Keywords: micromechanical based; model; based model; liquid crystal; crystal elastomers; stimulus responsive

Journal Title: International Journal of Solids and Structures
Year Published: 2021

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